Visible Light Copper Photoredox-Catalyzed Aerobic Oxidative Coupling of Phenols and Terminal Alkynes: Regioselective Synthesis of Functionalized Ketones via C≡C Triple Bond Cleavage (VSports)

Photoredox Catalysis with Metal Complexes Made from Earth‐Abundant Elements

Larsen1, Wenger2 2017Chemistry A European J37673160Get access via publisherAdd to dashboardCite Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task. Show abstract Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task. show abstract“…Hwang and co-workersa lso succeeded in performing the direct oxidative coupling of phenols and terminal alkynes using CuCl as ak ey ingredient. [66] This method allowed the regioselectives ynthesis of 47 different hydroxy-functionalized aryl and alkyl ketones (123)( Scheme30b). Photoinduced SET from Cu I -phenylacetylide to O 2 seems to be ak ey step, and 18 O-labelinge xperiments indicate that the oxygen atom in the ketonep roducts originate from O 2 . P resumably,aCu II superoxo complex that is formed concurrently can oxidizep henol to benzoquinone, and the latter undergoes Paterno-Büchi type [2+ +2] cycloaddition to Cu II -phenylacetylide to form an oxotene ring. …”Section: Reviewmentioningconfidence: 99%“…[65] b) Oxidative couplingo fphenols andterminal alkynes to yieldfunctionalized ketones. [66] sible addition-fragmentation chain transfer (RAFT). It was noted that [Zn(TPP)] (TTP = tetraphenylporphyrin) is unique when comparedt oC u, Ir,o rR ub ased sensitizers, in that it selectively activates trithiocarbonateso ver other thiocarbonylthio compounds, presumably due to specific molecular recognition. …”Section: Reviewmentioningconfidence: 99%

Photoredox Catalysis with Metal Complexes Made from Earth‐Abundant Elements

Larsen1, Wenger2 2017Chemistry A European J37673160Get access via publisherAdd to dashboardCite Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task. Show abstract Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task. show abstract“…27 The scope of the transformation is very broad. Terminal alkynes possessing aryl, vinyl-, and alkyl groups can be employed, resulting in ketone products 61a-e in good to excellent yields (Scheme 17). …”Section: Visible Light-induced Cu-catalyzed Reactionsmentioningconfidence: 99%

Visible light-induced transition metal-catalyzed transformations: beyond conventional photosensitizers

Parasram1, Gevorgyan2 2017Chem. Soc. Rev. 43222100Get access via publisherAdd to dashboardCite Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task. Show abstract Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task. show abstract“…(42,43). By contrast, the coupling between phenylacetelyneHossain et al, Science 364, eaav9713 (2019Cooperative photoredox dual catalysis. …”mentioningconfidence: 99%

Copper’s rapid ascent in visible-light photoredox catalysis

Hossain1, Bhattacharyya2, Reiser3 2019Science66034201Get access via publisherAdd to dashboardCite Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task. Show abstract Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task. show abstractScite is an AI-powered research tool that helps researchers better discover and evaluate scientific literature through Smart Citations—a revolutionary system that shows whether articles support, contrast, or simply mention a given claim. Founded in 2018, and now part of Research Solutions, Scite has indexed over 1 VSports app下载. 4 billion citations and partnered with more than 30 major publishers to provide researchers with unparalleled access to scientific literature. With its Scite Assistant, Smart Citation Index, and advanced search capabilities, the platform addresses critical challenges such as information overload and research reproducibility. Trusted by two million active users worldwide, Scite is reshaping how researchers interact with scholarly content—building ethical, transparent AI tools that support rigorous, copyright-compliant research.