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. 2017 Feb 6;56(3):1023-1026.
doi: 10.1021/acs.inorgchem.6b02165. Epub 2017 Jan 6.

"V体育安卓版" Copper Complexes as Bioinspired Models for Lytic Polysaccharide Monooxygenases

Alda Lisa Concia  1 , Maria Rosa Beccia  2 , Maylis Orio  1 , Francine Terra Ferre  3 , Marciela Scarpellini  3 , Frédéric Biaso  2 , Bruno Guigliarelli  2 , Marius Réglier  1 , A Jalila Simaan  1
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"VSports最新版本" Copper Complexes as Bioinspired Models for Lytic Polysaccharide Monooxygenases

Alda Lisa Concia (VSports在线直播) et al. Inorg Chem. .

Abstract

We report here two copper complexes as first functional models for lytic polysaccharide monooxygenases, mononuclear copper-containing enzymes involved in recalcitrant polysaccharide breakdown. These complexes feature structural and spectroscopic properties similar to those of the enzyme. In addition, they catalyze oxidative cleavage of the model substrate p-nitrophenyl-β-d-glucopyranoside. More importantly, a particularly stable copper(II) hydroperoxide intermediate is detected in the reaction conditions. VSports手机版.

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