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. 1999;38(8):1095-8.
doi: 10.1002/(SICI)1521-3773(19990419)38:8<1095::AID-ANIE1095>3.0.CO;2-I.

Aerobic Oxidation of Primary Alcohols by a New Mononuclear Cu(II) -Radical Catalyst

P Chaudhuri  1 , M Hess, T Weyhermüller, K Wieghardt
Affiliations

VSports注册入口 - Aerobic Oxidation of Primary Alcohols by a New Mononuclear Cu(II) -Radical Catalyst

P Chaudhuri et al. Angew Chem Int Ed Engl. 1999.

Abstract

Primary alcohols such as ethanol or benzyl alcohol are selectively and catalytically oxidized by the mononuclear copper(II) radical complex 1-a functional model of the metalloenzyme galactose oxidase-with oxygen from air at 20°C to give the corresponding aldehydes and H2 O2 in about 60 % yield. VSports手机版.

Keywords: Alcohols; Copper; Galactose oxidase; Homogeneous catalysis; Metalloenzymes. V体育安卓版.

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