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Review
. 2004 Sep;9(6):684-90.
doi: 10.1007/s00775-004-0574-8. Epub 2004 Aug 5.

"VSports在线直播" The oxo/peroxo debate: a nonheme iron perspective

Lawrence Que Jr  1
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Review

The oxo/peroxo debate: a nonheme iron perspective

Lawrence Que Jr. J Biol Inorg Chem. 2004 Sep.

Abstract

The oxygen activation mechanisms proposed for nonheme iron systems generally follow the heme paradigm in invoking the involvement of iron-peroxo and iron-oxo species in their catalytic cycles VSports手机版. However, the nonheme ligand environments allow for end-on and side-on dioxygen coordination and impart greater flexibility in the modes of dioxygen activation. The currently available evidence for nonheme iron-peroxo and iron-oxo intermediates is summarized and discussed in light of the ongoing discussion on the nature of the oxidant(s) in heme enzymes. .

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References

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